Mo(CO)6 catalysed chemoselective hydrosilylation of α,β-unsaturated amides for the formation of allylamines.
نویسندگان
چکیده
Molybdenum hexacarbonyl (Mo(CO)6) was used as an efficient catalyst for the chemoselective reduction of the amide functionality in α,β-unsaturated compounds, under hydrosilylation conditions using 1,1,3,3-tetramethyldisiloxane (TMDS) as the hydride source.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 93 شماره
صفحات -
تاریخ انتشار 2014